ࡱ> %` RbjbjNN<,,;<Z$$$$$$$8,,,8,-8nJ\.\.4...k/k/k/IIIIIII$,MhO<IE$v0k/k/v0v0I$$..J 444v0$.$.I4v0I44wD|$$E.P. !yگ,1`DcHD2J<nJEO|2rO$EO$Ek//4/ /k/k/k/II3k/k/k/nJv0v0v0v0888" 888"888$$$$$$ MATERIAL SAFETY DATA SHEET Product: Titanium Dioxide, Titanium White Effective Date: 01/18/2005 ------------------------------------------------------------------------------------------------------------------------ Section 1: Product Identification Synonyms: Titanium Dioxide, Titanium White HS No.: 3206 1110, CAS No.: 13463-67-7 CI No.: Pigment White 6 / 77891 Molecular Weight: 79.90 Chemical Formula: TiO2 GRADES COVERED BY THIS MSDS INCLUDE: ZA-100, ZR-940, ZR-940+, ZR-948, ZR-960, ZR-969, ZR-965 ------------------------------------------------------------------------------------------------------------------------ Section 2: Composition/Information on Ingredients Product codeTi02 content (%)Ingredients & content% ZA-100e"98.5/ZR-940&940+e"92.0Al203 0-3.0 SiO2 0-1.5ZR-948e"93.0Al203 0-4.5; modified with organic compoundsZR-960e"92.0Al203 0-3.0 ; SiO2 0-3.0;modified with organic compounds ZR-969e"93.0ZrO2 0-1.0: Al2O3 0-3.0; modified with organic compoundsZR-965e"97.0Al203 0-2.5; modified with organic compounds *GLOBAL pigments consist essentially of titanium dioxide particles. Most Grades have a surface coating of other metal oxides (or hydrated oxide) and A surface treatment of organic which are not classified as hazardous to health. ------------------------------------------------------------------------------------------------------------------------ Section 3: Hazards Identification 3.1 Potential Health Effects Eye contact may cause eye irritation with tearing, pain or blurred vision. Repeated skin contact with Titanium Dioxide may cause drying or cracking of the skin in sensitive individuals. Short-term overexposure by inhalation to Titanium Dioxide may cause irritation of nose,throat, and lungs with cough,difficulty breathing or shortness of breath.Results of a Global epidemiology study showed that employees who had been exposed to Titanium Dioxide were at no greater risk of developing lung cancer than were employees who had not been exposed to Titanium Dioxide. No pulmonary fibrosis was found in any of the employees and no association was observed between Titanium Dioxide exposure and chronic respiratory disease or x-ray abnormalities. Based on the results of this study Global concludes that Titanium Dioxide will not cause lung cancer or chronic respiratory disease in humans at concentrations experienced in the workplace. Inhalation of Amorphous Silica may cause drying of mucous membranes and irritation of nose, throat, and lungs with nosebleeds, cough, difficulty breathing or shortness of breath.Based on animal experiments, long term exposures to high doses could lead to pulmonary inflammation and subsequent development of chronic lung disease. Amorphous Silica does not induce the lung effects associated with crystalline silica. Epidemiology studies have not shown any evidence of fibrosis in workers exposed to Amorphous Silica dust levels ranging from 2 mg/m3 to 7 mg/m3. Increased susceptibility to the effects of Amorphous Silica may be observed in persons with pre-existing disease of the lungs. 3.2 Carcinogenicity Information None of the components present in this material at concentrations equal to or greater than 0.1% are listed as a carcinogen. ------------------------------------------------------------------------------------------------------------------------ 4. First Aid Measures Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration.If breathing is difficult, give oxygen. Call a physician. Skin Contact: The compound is not likely to be hazardous by skin contact but cleansing the skin after use is advisable. Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Ingestion: No specific intervention is indicated as compound is not likely to be hazardous by gestion. However, if symptoms occur, consult a physician. ------------------------------------------------------------------------------------------------------------------------ 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Flammable Properties: Will not burn. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Any media as appropriate for combustibles in area. Fire Fighting Instructions: None. ------------------------------------------------------------------------------------------------------------------------ 6. Accidental Release Measures 6.1 Safeguards (Personnel) NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. 6.2 Accidental Release treatment For dry product, shovel into covered container for disposal. Flush residue to wastewater treatment system. ------------------------------------------------------------------------------------------------------------------------ 7. Handling and Storage 7.1 Handling (Personal) In the manufacture of titanium dioxide, product is packaged at temperatures of approximately 100 to 120 Centigrade (212 to 248 Fahrenheit). When pigment is shipped shortly after manufacture, it may stay hot for a very long time depending on ambient temperatures and inventory storage practices Due to the potential of elevated pigment temperature, caution should be used while handling pigment and in solvent applications. Each work environment must be assessed to determine hazards. The following caution is provided for grades packaged in plastic bags: CAUTION: Plastic bag material may cause static ignition hazard in the presence of flammable or explosive vapor/air mixtures. Do not handle or use bags in the presence of flammable or explosive vapor/air mixtures. For dry product avoid breathing dust. Use dust filter respirator if exposure limits are exceeded (see Personal Protective Equipment). 7.2 Storage Based on Globals product storage experience, we recommend the following guidelines for safely stacking pallets of "GLOBAL" Titanium Dioxide: * All "GLOBAL" Titanium Dioxide grades packaged in paper or plastic bags should not be stacked more than three pallet high. Protect containers of dry product from damage. ------------------------------------------------------------------------------------------------------------------------ 8. Exposure Controls/Personal Protection 8.1 Engineering Controls Good general ventilation should be provided to keep dust concentrations below the exposure limits. 8.2 Personal Protective Equipment If exposure limits are exceeded for dust or dried-down product, a NIOSH approved air purifying respirator with ppropriate particulate filter should be used. Protective gloves should be worn to prevent prolonged skin contact with alkaline slurries. For dry product or dried-down product use a protective barrier cream and/or protective gloves to prevent skin contamination. Eye protection (minimum: safety glasses with side shields) is also required when handling titanium dioxide. 8.3 Exposure Guidelines Applicable Exposure Limits TITANIUM DIOXIDE PEL (OSHA) : 15 mg/m3, total dust, 8 Hr. TWA TLV (ACGIH) : 10 mg/m3, total dust, 8 Hr. TWA, A4 AEL * (Global) : 10 mg/m3, total dust, 8 Hr. TWA 5 mg/m3, respirable dust, 8 Hr. TWA *AEL is Globals Acceptable Exposure Limit. Where overnmentally imposed occupational exposure limits which are lower than the AEL are in effect,such limits shall take precedence. ------------------------------------------------------------------------------------------------------------------------ 9. Physical and Chemical Properties Physical Data Boiling Point : Not applicable Vapor Pressure : Not volatile Vapor Density : Not volatile Melting Point : Not applicable Evaporation Rate : Not volatile Solubility in Water : Insoluble pH (water extract) : 6.0-8.5 Odor : Odorless. Form : Powder, solid Color : White Specific Gravity : 4.0 - 4.2 ------------------------------------------------------------------------------------------------------------------------ 10. Stability and Reactivity Chemical Stability: Stable under ordinary conditions of use and storage. Incompatibility with Other Materials: None reasonably foreseeable. Decomposition: Decomposition will not occur. Polymerization: Polymerization will not occur. ------------------------------------------------------------------------------------------------------------------------ 11. Toxicological Information ANIMAL DATA Some (but not all) grades of "GLOBAL" Titanium Dioxide contain Amorphous Silica. "GLOBAL" Titanium Dioxide Oral ALD : >24,000 mg/kg in rats Dermal ALD : >10,000 mg/m3 in rabbits Inhalation 4-hour ALC : >6.82 mg/L in rats Amorphous Silica Oral LD50 : >10,000 mg/kg in rats The product contains Titanium Dioxide which is a slight (HMIS scale) or moderate (Global scale) eye irritant and a slight skin irritant, but is not a skin sensitizer in animals. This product may contain Amorphous Silica which is a mild eye irritant and is a negligible to slight skin irritant when tested as a 50% aqueous paste in animals. Amorphous Silica dust is not expected to be a skin irritant. Animal testing indicates Amorphous Silica is not a skin sensitizer. In short term inhalation studies of Titanium Dioxide mixtures containing 6% Aluminum Hydroxide and 8% Silicon Dioxide, a slight fibrogenic response occurred in animals exposed to 1,300 mg/m3 for 4 weeks respirable dust. A typical dust cell reaction but no fibrogenic response was noted in animals similarly exposed to Titanium Dioxide, or Titanium Dioxide mixtures containing from 1% to 3% Aluminum Hydroxide, and 2.7 to 6% Silicon Dioxide. Repeated inhalation exposure to Amorphous Silica caused pulmonary changes including reversible inflammation. Long-term exposure caused pulmonary changes including reversible inflammation, vascular obstruction and emphysema. Guinea pigs exposed to Aluminum Hydroxide by inhalation exhibited no evidence of injurious effects but did show progressive accumulation of aluminum in the lungs. Repeated and long term ingestion of Titanium Dioxide caused no significant toxicological effects. Single, repeated and long-term exposure by ingestion to Amorphous Silica caused no significant toxicological effects. Ingestion of Aluminum Hydroxide caused growth impairment, and bone changes due to phosphate depletion in animals but ingestion of phosphate eliminates these changes; no evidence of other toxicity was noted. In lifetime inhalation studies of respirable Titanium Dioxide at levels up to 250 mg/m3, no compound-related clinical signs of toxicity were seen in the exposed animals.Slight pulmonary fibrosis was seen at 50 and 250 mg/m3 respirable dust levels but not at 10 mg/m3. There was no evidence of cancer in animalsexposed to 10 or 50 mg/m3 respirable Titanium Dioxide. Microscopic lung tumors were seen in 17 percent of the rats exposed to 250 mg/m3 respirable Titanium Dioxide. The lung tumors seen in the rat were different from common human lung cancers, relative to anatomic type and location, occurred only at dust levels which overwhelmed the animals lung clearance mechanism and, therefore, are of estionable biological relevance for man. In lifetime animal feeding tests at levels up to 50,000 ppm,Titanium Dioxide showed no evidence of cancer or other significant adverse effects in either rats or mice. No animal data are available to define the developmental or reproductive toxicity of Titanium Dioxide. Tests have shown that Titanium Dioxide does not cause genetic damage in bacterial or mammalian cell cultures, orin animals. Animal testing indicates Amorphous Silica does not have carcinogenic or reproductive effects. Amorphous Silica has not produced genetic damage in bacterial cultures. ------------------------------------------------------------------------------------------------------------------------ 12. Ecological Information Environmental Information: Aquatic Toxicity Environmental Toxicity: 96 hour LC50, fathead minnows: >1,000 mg/L ------------------------------------------------------------------------------------------------------------------------ 13. Disposal Considerations Comply with country and local regulations. If approved, remove to land disposal area. ------------------------------------------------------------------------------------------------------------------------ 14. Transport Information Shipping Information: Not Regulated as a hazardous material by DOT, IMO, or IATA. Shipping Containers: Tank Cars, Tank Trucks, Flexible Intermediate Bulk Containers, Tote Bins, Bags, etc. ------------------------------------------------------------------------------------------------------------------------ 15. Regulatory Information Acute : Yes Chronic : No Fire : No Reactivity : No Pressure : No Extremely Hazardous Substance -No CERCLA Hazardous Substance -No Toxic Chemical -No ------------------------------------------------------------------------------------------------------------------------ 16. Other Information Personal Protection rating to be supplied by user depending on use conditions. NFPA Ratings: Health: 0 Flammability: 0 Reactivity: 0 Label Hazard Warning: CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. NUISANCE DUST. Label Precautions: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid breathing dust. Keep container closed. Use with adequate ventilation. Label First Aid: In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. If irritation develops call a physician. If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. Additional Information: MEDICAL USE CAUTION: Do not use in medical applications involving permanent implantation in the human body. For other medical applications see Global CAUTION Bulletin. Product Use: As fine white pigments on rubber, plastic, paper, coating and organic resin etc industry products produce. Re-mark: ******************************************************************************************************* WE provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. 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